Double Click Middle Button in a view = Zoom to Fit
Double Click on a component Family = Edit the Family (open in the family editor)

Some people like the new Stairs functionality?
http://blogs.rand.com/architectural/2012/03/what-really-matters-for-2013.html

Sketch stairs can be added to an Assembly, but Component Stairs can’t…

Multi-segmented grids:
To create a multi-segmented grid, select the Multi-segment tool in the Draw panel of the Modify|Place Grid context tab.  This will enable sketch mode for you to draw the grid line.  This will work on linear and radial grids or a combination of lines and arcs in the sketch, but must be a continuous segment.
http://blogs.rand.com/support/2012/03/revit-2013-miscellaneous-improvements.html

Arc grids are also available:

1. Warning message displays if the current selection contains elements that cannot be included in an assembly.
The following elements cannot be included in an assembly:
  • Annotations and detail items
  • Assemblies and elements that are already part of another assembly
  • Complex structures (trusses, beam systems, curtain systems, curtain walls, stacked walls)
  • Elements in different design options
  • Groups
  • Imports
  • Images
  • Links or elements in a link
  • Masses
  • MEP-specific elements (ducts, pipes, conduits, cable trays and fittings, HVAC zones)
  • Model lines
  • Rooms
  • Structural loads, load cases, and internal loads

See the rest at:
Assembly Usage Tips – WikiHelp